高流速高分辨辉光放电质谱法测定粉末高温合金中26种微量和痕量元素

准确测定粉末高温合金中微量及痕量元素,对粉末高温合金的生产、应用具有重要意义。将样品在放电电流40～45 mA,放电电压1 100～1 200 V,氩气流速400～450 mL/min下进行辉光放电激发,选择合适的同位素和分辨率以消除质谱干扰,使用基体匹配的内控标准样品和标准物质校准各待测元素的相对灵敏度因子(RSF),实现了高流速高分辨辉光放电质谱法(GDMS)对粉末高温合金中硼、钠、镁等26种微量及痕量元素的测定。采用实验方法对粉末高温合金内控样品中26种微量及痕量元素进行测定,各待测元素的测定值与参考值基本一致,测定结果的RSD(n=6)在0.9%～15.4%之间。采用实验方法对粉末高温合金样品进行测定,测定结果分别与电感耦合等离子体原子发射光谱法(ICP-AES)测定硼、铁和锆,高频感应燃烧红外吸收法测定硫,原子荧光光谱法测定硒,高分辨电感耦合等离子体质谱法(HR-ICP-MS)测定其余元素(钠、镁、硅、磷、钙、钒、锰、铜、镓、砷、银、锡、锑、碲、镧、铈、铪、钽、铊、铅和铋)的结果保持一致,测定结果的RSD(n=6)在0.2%～26.6%之间。     

Dressing of filigree fine-grained metal bonded grinding wheels

Metal bonded grinding tools offer a remarkable potential for micro grinding because of their favorable wear behavior. However, metal bonded grinding tools, especially dicing blades, are hard to dress by conventional dressing methods. Electro contact discharge dressing, which is presented in this paper, is a numerically controlled dressing process offering the possibility to create the geometry and topography of the grinding wheel simultaneously at negligible dressing forces. The power of an electric circuit thermally removes the metal bond of the grinding wheel during the dressing process. The quality of the created profiles and the influence of the dressing parameters on the specific material removal rate of the grinding tool as well as the wear of the electrode are investigated at fine-grained grinding wheels.     

钨尾矿微晶玻璃的形状记忆效应

研究了钨尾矿微晶玻璃的形状记忆效应（ＳＭＥ），并用Ｘ射线衍射法（ＸＲＤ）作了相分析。结果表明，钨尾矿微晶玻璃具有明显的ＳＭＥ；恢复应变随回复保温温度升高而增加；该材料随着变形量的减小，形状恢复率随之上升     

不同Co含量Mm（NiCoMnAl）5贮氢合金的低温放电特性

用电化学方法研究了-40℃条件下Co含量对AB5型贮氢合金的放电容量、氢化物分解的稳定性及氢在贮氢合金中的扩散系数等的影响。结果表明：随Co含量的增大，晶胞体积增大，氢化物分解的焓变增大，低温放电容量减小。氢扩散是影响贮氢合金的低温放电性能的重要因素。     

Mn含量对Mg2Ni型合金相形成及放电性能的影响

采用按比例混合合金粉末压制成圆柱试样，然后用低温烧结和随后机械球磨的方法制备了非晶态的Mg2Ni型合金。研究了烧结和球磨对不同Mn含量的Mg2Ni型合金的相形成过程及电化学性能的影响。实验表明：在Mg2Ni中采用第三组元Mn对Mg进行适量的替代后，通过烧结及球磨方法可以获得均匀的非晶相；微量替代可有效地提高其放电容量：随替代量的增加，合金最大放电容量和高速放电能力降低，而充放电循环稳定性提高。     

Study On the Tribological Behavior of the Arc-added Glow Discharge Plasma Non-hydrogen Carburization On Titanium Alloy Surfaces

This paper introduces a new titanium alloys surface strengthening treatment by using the arc-added glow discharge plasmas non-hydrogen carburization technique. High purity and high strength graphite is selected as cooling cathode arc source for supplying carbon atoms and particle, which migrate to the titanium alloy(Ti6Al4V) surface and form modified layer. Thus, the hydrogen embrittlement is avoided while the tfibological behavior of the titanium alloy surface is improved in the respects of anti-friction and anti-wear ability.The tribological behavior of the modified layer under dry sliding against SAE52100 steel was evaluated on a ball-on-disc test rig. The results showed that the modified layer obtained a thickness of 30μm at 980℃, 30minutes. The microhardness of the Ti6Al4V alloy surface attained 936 HV, which was much larger than that of the Ti6AI4V alloy. The Ti6AI4V alloy was characterized by adhesion wear and scuffing under dry sliding against the steel, while the surface modified layer experienced much abated adhesion wear and scuffing under the same testing condition. This could be attributed to the carbon dement with different modalities exists in the modified layer.The modified layer showed good friction-reducing and fair anti-wear ability in dry sliding against the steel. Using the SEM,XRD and XPS, the phase structure and morphology of the carburization modified layer was analyzed.     

An investigation of ultrasonic-assisted electrical discharge machining in gas

This study focuses on using ultrasonic to improve the efficiency in electrical discharge machining (EDM) in gas medium. The new method is referred to as ultrasonic-assisted electrical discharge machining (UEDM). In the process of UEDM in gas, the tool electrode is a thin-walled pipe, the high-pressure gas medium is applied from inside, and the ultrasonic actuation is applied onto the workpiece. In our experiment, the workpiece material is AISI 1045 steel and the electrode material is copper. The experiment results indicate that (a) the Material Removal Rate (MRR) is increased with respect to the increase of the open voltage, the pulse duration, the amplitude of ultrasonic actuation, the discharge current, and the decrease of the wall thickness of electrode pipe; and (b) the surface roughness is increased with respect to the increase of the open voltage, the pulse duration, and the discharge current. Based on experimental results, a theoretical model to estimate the MRR and the surface roughness is developed.     

40Cr钢电火花表面强化层的磨损特性研究

分析了在大接触应力的磨损条件下,表面残余应力和硬度对40Cr电火花强化层耐磨性的影响,探讨了其磨损机理。结果表明:滚动磨损和滚、滑动磨损时,随着试样表层硬度的提高,试样的耐磨性增大;强化层中的残余压应力可以提高强化层的硬度并增强其耐磨性。滚动磨损时,电火花强化层的磨损方式主要为粘着磨损、疲劳磨损和磨粒磨损三种机制;在滚、滑动磨损时,除上述三种机制外,还发生了氧化磨损。     

论新型氮肥——长效碳酸氢铵

介绍了碳酸氢铵产品的诞生、沿革及现状;论述了长效碳铵的改性机理、供肥能力、生产工艺、农用效果;揭示了长效碳铵对CO2的减排和固定效应;阐明了开发生产新型氮肥——长效碳酸氢铵对改善生态环境和服务农业的重要意义。     

尾煤泥水煤浆高效制浆工艺在临涣选煤厂的应用

分析了临涣选煤厂浮选尾煤的性质及成浆性。为了把高粘性尾煤泥滤饼制备成水煤浆，研制了循环剪切桶和剪切泵。实践证明，浮选尾煤泥可以制备出浓度高、稳定时间长和流变性好的水煤浆。研制的制浆设备结构紧凑、电耗低、效率高。笔者介绍了该设备的结构、工作原理以及制浆生产线。